Researchers by Faculty

Pharmacy

Dr. Rafik Karaman: Removal of Antibacterial Agents by Advanced Membrane Technology and ODTMA-Micelle-Clay Comlex

Field of Research: Analytical Chemistry

Name of author) (s): Mohammad Awwad, Fuad Al-Rimawi, Mustafa Khamis, Shlomo Nir, Samer Khalaf, Amin Thawabteh and Rafik Karaman

Title of published work: Removal of Antibacterial Agents by Advanced Membrane Technology and ODTMA-Micelle-Clay Comlex.

Name of Journal: Journal of Case Studies

Year: 2015

Volume:  4, Issue 5

Pages: 143-164

Publisher: N/A

Abstract:

The efficiency of sequential advanced membrane technology wastewater treatment plant towards removal of amoxicillin and cefuroxime  axetil  from  wastewater  was  investigated.  The  sequential  system  included  activated  sludge,  ultrafiltration  (hollow fiber membranes with 100 kDa cutoff, and spiral wound membranes with 20 kDa cutoff), activated carbon column and reverse osmosis (RO). The overall performance of the integrated plant showed complete removal of amoxicillin and cefuroxime axetilfrom spiked wastewater samples. The adsorption isotherms for these compounds have been studied using both activated carbon adsorbent and newly developed adsorbent  named micelle-clay  complex (octadecyltrimethylammonium(ODTMA)–clay  (montmorillonite)). The  results  revealed  that both isotherms adsorption fit the Langmuir equation with Qmaxof 100 mg/g and 90.91 mg/g,and with K values0.229 L/mg and 0.158 L/mgfor amoxicillin using activated carbon and micelle-clay complex, respectively, and with Qmaxof 26.31 mg/g and 31.25 mg/g and with  K  values0.271  L/mg  and  0.122  L/mg for  cefuroxime  axetil  using  activated  charcoal  and micelle-clay complex,  respectively. Removal of amoxicillin and Cefuroxime axetilfrom polluted waterin high concentrations (100 ppm) by column filter including a mixture  of  micelle-clay  or activated  charcoalcomposite  with  sand  indicated an efficient  removal of  both  pharmaceuticals.

Keywords:

Antibiotics;  Amoxicillin;  Cefuroxime  axetil;  Wastewater;  ultrafiltration;  Activated  carbon;  Clay  micelle  complex; Adsorption.

Contact author (s):

Name: Rafik Karaman, PhD.

Address: Al Quds University, Faculty of Pharmacy

E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

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